Cogeneration in Palm Oil Mills with Pyrolysis, Initial Steps in Biochar Production and Implementation

The analogy is like cofiring carried out in coal-fired power plants by mixing biomass fuels with a certain ratio as an effort to decarbonize the energy sector in power plants. While in palm oil mills, cogeneration with pyrolysis is an innovative initial step to enter the carbon negative era with the application of biochar, the main product of pyrolysis. And because all palm oil mills use biomass fuel for their mill operations, they are already based on carbon neutral fuel, unlike coal-fired power plants which are based on carbon positive fuels because they come from fossils.

Unlike cofiring which mixes coal and biomass fuels with a certain ratio and then burns them together in a furnace such as pulverized combustion, cogeneration is done by producing energy separately but the energy output is for the same use or especially the same boiler. This is done because the types of fuels may be different, such as solid fuels with liquid fuels or the technology for producing the energy is different. With this cogeneration, it means that not all energy is produced from one energy source or energy from cogeneration is a secondary energy source to meet total energy needs, and in the case of cogeneration in this palm oil mill, energy from combustion is still the primary energy.

Then why not just do full pyrolysis? It is easier, gradually for palm oil mills to adopt pyrolysis technology and its characteristics. Because (slow) pyrolysis aims to maximize solid / biochar, the by-products in the form of excess energy (syngas and biooil) as a source of boiler fuel, the calorific value is not as much as combustion which is indeed intended to maximize heat. Only about 1/3 of the excess energy contributes (cogeneration) as boiler fuel. In other words, if full pyrolysis is carried out directly, the amount of biomass as raw material for pyrolysis becomes 3 times greater or the pyrolysis unit becomes very large so that all palm oil mill biomass waste is used, and the mill cannot sell its palm kernel shells.

What are the benefits obtained by palm oil mills if they carry out cogeneration with pyrolysis for biochar production? Among the biochar products, it can save fertilizer use in oil palm plantations, overcome the problem of empty oil palm bunches (EFB) so that palm oil mills can achieve zero waste, palm kernel shells (PKS) that have been used for boiler fuel can be sold to increase income, the productivity of fresh fruit bunches (FFB) of palm oil increases, the application of biochar in palm oil plantations is also a climate solution (carbon sequestration / carbon sink) so that it can get carbon credit compensation and with good waste management, even zero waste and the application of biochar in palm oil plantations, palm oil companies will get a good image in terms of the environment and sustainability.  

Maximizing the Rate of CO2 Absorption from the Atmosphere Based on Biomass

Maximizing the rate of CO2 absorption from the atmosphere is very important considering the rate of addition of CO2 concentration to the atmosphere is not comparable to the rate of CO2 absorption. This is what makes the CO2 concentration continue to increase. To balance this speed, a strategy is needed to increase the rate of CO2 absorption. The use of biomass will be very effective and provide multiple benefits for human life. 

CO2 from the atmosphere needs to be captured through biomass production through the process of photosynthesis in plants. Fast-growing species of plants that have high photosynthesis rates are needed for this. Furthermore, biomass, especially wood from fast-growing species of plants, is used as raw material for biochar. Furthermore, biochar is used to improve soil fertility (soil amendment) in various types of agricultural and forestry plants.

Biochar production with slow pyrolysis will also produce excess heat, syngas and biooil that can be used as energy sources. The benefits of biochar production will be obtained from the sale of biochar, the sale of carbon credits and the use of slow pyrolysis by-products. With conditions like this, efforts to increase the speed of CO2 absorption from the atmosphere should be increased. How fast and how much CO2 volume can be absorbed will depend on the type of fast growing species used, the area of ​​planting and the capacity of biochar production.

Biochar or Biocoal Production?

Biochar and biocoal production are basically one breath. Biochar production with full pyrolysis while biocoal with half/mild pyrolysis (torrefaction). The purpose of torrefaction/mild pyrolysis is to increase its energy content and make it hydrophobic so it is called biocoal. While the purpose of full pyrolysis is to produce stable biocarbon material so that it does not decompose in the soil for hundreds or even thousands of years and improve soil fertility so as to increase plant productivity (agriculture and forestry). 

Current biochar applications are mainly for agriculture and biochar production will produce excess heat, syngas and biooil as energy sources. While biocoal only focuses on energy. The benefits of biochar production are obtained from the sale of biochar, the sale of carbon credits and the utilization of by-products (full) pyrolysis. While the benefits of biocoal are only from the sale of biocoal itself.

The selection or development of a business will be related to business readiness (market, technology, investment, etc.) and other benefits, namely benefits in the social and environmental sectors.

Biochar from Wood Waste and Forestry Waste

The era of decarbonization and bioeconomy continues and continues to grow over time. While some people focus on the carbon neutral sector such as the production of biomass fuels such as wood pellets, wood briquettes or wood chips, people who focus on negative carbon seem to be fewer, including the use of CCS (Carbon Capture and Storage) and biochar production. Compared to CCS, biochar production with pyrolysis is easier and cheaper so it is projected to become a future trend. Logically, the negative carbon scenario is actually much better because in addition to reducing the concentration of CO2 in the atmosphere, while the neutral carbon scenario only does not increase CO2 emissions in the atmosphere, but does not reduce or absorb CO2 in the atmosphere. CO2 sequestration or biochar carbon removal (BCR) is currently also the most industrially relevant carbon removal technology. BCR is a key solution for real climate change mitigation today and its development is very rapid. BCR also has a vital role in the carbon removal technology portfolio. 

 

Woody biomass, especially from wood industrial waste and forestry waste, is a potential raw material for biochar production, even this type of wood biomass is the best raw material because it can produce high quality biochar, namely fixed carbon of more than 80%. The potential for wood biomass raw materials in Indonesia is very large, estimated at 29 million m3/year from forest harvesting waste, and 2 million m3/year from wood processing industry waste including 0.78 million m3 in the form of sawdust (the yield of the sawmill industry ranges from 50-60% and as much as 15-20% consists of sawdust). And that does not include if there is a biomass plantation or energy plantation dedicated to biochar production.

With the condition of agricultural land, plantations and forestry which are experiencing a lot of degradation, the need for biochar is also very large. Among the factors causing the decline in land fertility is the use of chemical fertilizers and pesticides for decades continuously and tends to be excessive. This causes a decline in soil quality which has an impact on crop production because it makes the land more acidic and hard which is estimated to reach millions of hectares. In addition, the price of chemical fertilizers is increasingly expensive and difficult to obtain, which results in low agricultural production, so the government is forced to import several agricultural commodities to meet the needs of the community. This actually does not need to happen considering the potential land in Indonesia is very large, it only needs to improve the condition of the land so that it can be optimal again. Making damaged land fertile is not difficult, it only takes perseverance to repair and care for the land so that it continues to be fertile.

Meanwhile, dry land consists of ultisol soil of 47.5 million ha and oxisol of 18 million ha. Indonesia has a coastline of 106,000 km with a potential land area of ​​1,060,000 ha, generally including marginal land. Millions of hectares of marginal land are spread across several islands, have good prospects for agricultural development but are currently not well managed. The land has a low fertility rate, so technological innovation is needed to improve and increase its productivity. Not to mention post-mining land which is almost all very damaged and also covers millions of hectares. And biochar is the right solution that can restore the condition of the land to be fertile again. 

Slow pyrolysis is the best technology for biochar production. But the technology used must be efficient and emissions meet the threshold standards of the country concerned. In addition, excess heat and/or liquid products and gas products from pyrolysis should also be utilized. With the criteria for pyrolysis technology as above, in addition to the quality and quantity of products, namely biochar, can be maximized, the production process also does not cause new problems in the form of environmental pollution. This is very much in line with biochar business activities so that it becomes a solution to the problem of industrial biomass waste from wood and forestry waste as well as a solution to climate problems. Even the utilization of by-products (excess heat and/or liquid products and gas products from pyrolysis) can also encourage the emergence of other environmentally friendly and renewable products.

In economic terms, the outline can be as follows, namely with an investment of 10 million US dollars, approximately 200,000 tons of biochar with more than 400,000 carbon credits will be produced over a period of 10 years. Or if with an investment of 100 million US dollars, almost 2 million tons of biochar and more than 4 million carbon credits will be produced over a period of 10 years. And for example, with a selling price of biochar of 100 dollars per ton and also a carbon credit of 100 dollars per unit (per ton of CO2), then within 10 years the investment has increased 6 times or it only takes about 1.7 years for the initial investment to return (payback period). Of course, when the price of biochar is higher and / or its carbon credits, of course the return on capital will be faster. And that does not include the utilization of liquid and gas products from pyrolysis and excess heat which also have economic potential that is no less interesting. The trend of the future business era will not only focus on financial profit but also provide solutions to environmental problems and climate problems, and of course solutions to social problems by creating jobs.    

Increasing Food Agriculture Productivity: Biochar Application or Forest Clearing for Food Estate?

Indonesia currently ranks 69th out of 113 countries in 2022 in food security and this is lower than Malaysia and Vietnam with indicator points below the global average. This condition is concerning considering that Indonesia was once self-sufficient in food before and even the price of rice in Indonesia is the most expensive in ASEAN. Efforts to maintain food productivity are indeed a challenge, let alone increasing it. Along with increasing population growth, the need for food automatically increases. The condition of declining food production and productivity is related to a number of factors including land conversion to non-agricultural land, and soil / land damage. A number of regulations have been made to stem the rate of decline in food productivity due to these two things.

Regarding land damage, repair efforts need to be made so that agricultural productivity increases. It is estimated that the area of ​​land damage that occurs is very large with a high level of severity. This requires gradual and sustainable repair efforts with various strategies including improving farming patterns and even a number of incentives. Only with these efforts can the agricultural sector as a source of food be repaired or if not, the damage to agricultural land will get worse so that repair efforts will be more difficult.

Biochar application or forest clearing for food estate ?
Biochar application will be able to repair damaged lands. In addition to being a slow-release fertilizer agent so that fertilizer use becomes efficient and does not pollute the environment, increasing soil pH, increasing soil organic carbon and increasing agricultural productivity, biochar will also help overcome the management of agricultural waste that has so far polluted the environment. The increase in agricultural productivity from the use of biochar is on average around 20%. If Indonesia's current rice production is around 31 million tons per year, then the application of biochar will increase total rice production to 37.2 million tons (an increase of 6.2 million tons). With an average rice production per hectare of 6 tons, the increase of 6.2 million tons is equivalent to increasing the area of ​​agricultural land by 1.03 million hectares. Even damaged land from post-mining can be reclaimed and rehabilitated with the application of biochar, with the land area also reaching millions of hectares. This is certainly better than clearing new forest land for food estates because of its environmental impact. 

As the human population grows, the need for food and energy will continue to increase. Indonesia's population in 2045 is estimated to reach 319 million people and the world's population in 2050 is approaching 10 billion people. The need and urgency of biochar to improve soil quality is increasing. Tens of millions of hectares of all Indonesian acidic soils, which are classified as dry land acidic soils, need to be improved with biochar. This means that the business potential reaches billions of dollars or trillions of rupiah. Meanwhile, rice imports in 2024 are targeted to reach 3.6 million tons (as a buffer), a large amount. With an annual rice requirement of around 31 million tons, the contribution of imported rice reaches more than 10%.

Biochar in addition to repairing soil damage so that it increases its fertility which ultimately increases agricultural productivity is also part of the climate solution, namely by means of carbon sequestration. Biochar applied to the soil will last hundreds or even thousands years, and does not decompose. This is another advantageous factor for biochar producers, namely getting carbon credits. The quality of biochar will determine the acquisition or price of the carbon credit, so that the raw materials of biochar and its production process are affected. The price of carbon credits is increasing so that it is increasingly attractive and also the carbon credit market continues to grow.

Damage to land or agricultural land that occurs is mostly caused by excessive use of chemical fertilizers. If the use of chemical fertilizers can be reduced in dosage or with sufficient use, there will be improvements in land quality. Even if chemical fertilizers are gradually reduced in dosage and organic fertilizers / compost are increasingly added so that in the end chemical fertilizers are not used at all, soil fertility will be optimal as well as agricultural productivity.

The photo from here

Of course, this requires time and continuous effort. Livestock must also be encouraged so that compost / organic fertilizer can also be produced sufficiently from the processing of livestock manure. Integrated farming with livestock is the best solution for improving agricultural land with biochar, especially increasing the efficiency of fertilization. If the above can be implemented properly, then forest clearing for food estate land can also be slowed down / held back by considering all aspects comprehensively so that it is not a short-term solution that tends to be forced, and rushed because of the regime's image efforts even at a cost of hundreds of trillions.     

Utilization of Excess Energy from Biochar Production with Pyrolysis

Most of the production equipments for biochar are currently obsolete, so that the productivity and quality of the products produced are low, also causing environmental problems, namely air pollution. In equipment with this technology, the production process is also not running efficiently, indicated by the large amount of energy or heat loss so that it is less profitable. Slow pyrolysis technology is the best technology for biochar production because it maximizes the production of a solid fraction (biochar). Meanwhile, other thermal technology group are not so suitable for biochar production, for example fast pyrolysis, the main objective of which is to maximize its liquid product or biooil, gasification is the main objective of maximizing gas or syngas product as well as hydrothermal carbonization (HTC) or wet pyrolysis requiring high pressure operating conditions so that it is difficult to be applied. Modern slow pyrolysis technology will operate autothermal / self sustain fuel, safe, good process control and energy management, so that in this way in addition to energy being used for the pyrolysis process itself, excess energy can also be used for other needs such as electricity or heat production.

 There are three main variables for this pyrolysis process, namely heating rate, duration / residence time and temperature. The quality and quantity of biochar are determined by these process variables. For example, biochar production with a temperature of less than 400 C will produce acidic biochar, while biochar production above this temperature will produce alkaline biochar. Currently, the pH of biochar produced ranges from 4 to 12. There are also those who make a category about the pyrolysis temperature for biochar production, namely, low with less than 250 C, medium (250 - 500 C), high with more than 500 C. According to some researches fixed carbon also increased from 56% to 93% at 300 and 800 C pyrolysis temperatures. The surface area also increased from 120 m2 / gram at 400 C to 460 m2 / gram at 900 C. 

And indeed, basically the quality and quantity of biochar is determined by the raw materials used and the conditions of the production process, especially the pyrolysis. In fact, to ensure the quality of biochar, all aspects need to be considered such as raw materials and production processes such as the pyrolysis operating temperature should not be more than 20%, interruptions when production are allowed as long as the conditions of subsequent production parameters are maintained the same as before the restart. The composition of the raw material should not fluctuate more than 15%. And for modern pyrolysis equipment, the excess energy must be utilized with an estimated 35-60% of the energy from the biomass raw material found in pyrolysis gas. A number of agricultural waste processings can use the pyrolysis optimally, including:

 1. Palm Oil Industry

The use of pyrolysis technology for palm oil companies, especially in Indonesia, is currently ideal. This is because palm oil mills or CPO mills produce a lot of solid waste biomass namely, empty fruit bunches/EFB, fiber and palm kernel shell. And because palm kernel shell / PKS has a lot of demand both from within and outside the country for industrial fuel and power plants, this PKS should not be used as raw material for pyrolysis or biochar production, but can be directly used as a trading commodity.  The EFB and fiber are used as raw material for biochar and then the biochar is used to improve the soil quality of palm oil plantation so that fresh fruit bunch or FFB productivity increases. Excess energy from pyrolysis is then used as boiler fuel so that it can reduce or even replace all PKS as the the boiler fuel. And because the boiler fuel is replaced with the excess energy pyrolysis, so can be  all of the PKS can be sold. 

2. Integrated Coconut Industry

Products from coconut processing such as copra, dessicated coconut, and nata de coco require heat in the production process. Coconut shell charcoal is also a favorite charcoal with a large market demand. The charcoal will usually be further processed into briquettes for energy and activated carbon for various industries. For biochar production, coconut industrial wastes such as coir/fiber, bunch and midrib can be used. Excess energy of pyrolysis can be used for the production of the above products and other advanced products. The low productivity of Indonesian coconut production needs to be improved, one of which is by improving soil quality with biochar. In addition, there are so many coconut plantations in Indonesia that need to be replanted so that improving soil quality to achieve the desired production is increasingly important. 

3. Corn Plantation

Efforts to increase food products need to be taken seriously, this can be done in two ways, first by expanding the land or making new rice paddy fields for production and the second by improving the quality of existing land so that productivity will increase. Biochar is very effective and efficient for the second method above. Besides being used as a human food source, corn is also used for animal feed. With the projection of the human population continuing to increase, the need for food either directly by consuming corn or indirectly from livestock such as meat and eggs. Poultry or chicken feed production ranks first of other animal feed production, or in the world almost half of the animal feed produced is chicken feed. Corn cobs and husks are agricultural waste that can be used for biochar production. Excess energy from the pyrolysis process can be used for drying corn and other advanced processes.

4. Rice Paddy Farming 

Rice or paddy is the staple food of most of the Indonesian population. The area of irrigated rice fields is decreasing throughout the year. This encourages the use of non-irrigated rice fields or dry land for the production of this rice. Biochar is able to improve the quality of dry land soils, such as in corn farming. Rice husks are rice paddy agricultural waste that can be used for biochar production. Excess energy from rice husk pyrolysis can be used for drying the rice paddy itself so that it becomes dry grain ready to be milled, or for other purposes. With the improvement of soil quality, rice productivity can be increased and it is not impossible that food self-sufficiency, especially rice, can be achieved, as has been achieved by Indonesia some time ago.

Which is Better, Efficient Boiler or Pyrolysis System ?

Fiber and palm kernel shells (PKS) are palm oil mill solid wastes that are produced in CPO production in that mill. The amount of fiber and PKS waste is quite a lot, which is around 20% of each fresh fruit bunch (FFB) or almost the same as the CPO produced. A palm oil mill with a capacity of 60 tons / hour FFB can produce fiber as much as 8.1 tons per hour or 194.4 tons per day and PKS of 3.3 tons / hour per hour or 79.2 tons per day. And because both of them are waste, generally the utilization of the waste is not initially considered, including for use as fuel in boilers in palm oil mills for the production of electricity and steam. The use of fiber and PKS for boiler fuel generally uses 100% fiber and about 30% of the PKS. Under these conditions the remaining 70% of the PKS can be used for other things including being sold or even exported.

When the shell becomes a commercial commodity and demand is greater, palm oil mills replace their old inefficient boilers with new boilers that have a high level of efficiency. In this way, 100% of the PKS is no longer used to boiler fuel and only requires fiber as fuel. In this condition a paradigm shift in thinking begins to occur, that is when the solid waste is almost unnoticed and tends to be considered a problem, then it becomes an important part of earning additional income and it can even be estimated that if the shell is successfully sold then it is sufficient to cover the operational costs of the palm oil mill. Certainly something interesting if the production of CPO (crude palm oil) with 0% operational costs so that profit is increasingly attractive especially amid the recent decline in CPO prices.

Another thing that can be done is to use a pyrolysis unit, to run the boiler. With pyrolysis, not only fiber is used but also the empty fruit bunch (EFB). EFB are solid palm oil mill waste which to date have generally not been utilized. Besides producing energy, pyrolysis also produces products in the form of charcoal (biochar). Although charcoal (biochar) can also be used for energy sources, but in the business of palm oil companies the use of biochar for plantations can be more compatible. The use of biochar in palm oil plantations is mainly to  fertilizer saving, which is one of the major cost components (around 30%) in the CPO production business. With an area of ​​20 thousand hectares of oil palm plantations, fertilizer costs are estimated to reach Rp. 71.50 billion (around US$ 5 million) per year or Rp. 35.75 billion (around US$ 2.5 million) per year for every 10,000 hectares, for more details, please read here. Palm oil mills with big vision certainly try to maximize their potential with the aim of maximizing profits from upstream to downstream production activities. With Biochar can also target the increase in productivity of FFB, for more details, please read here.

The application of biochar will be easier to do in Indonesia than in Malaysia, this is because almost all palm oil mills in Indonesia also have palm oil plantations while in Malaysia the mills generally do not have their own palm oil plantations. The palm oil industry also has an important role for the two countries because Indonesia and Malaysia are the largest CPO producers and owners of biggest palm oil plantations in the world today. The palm oil industry contributes around 7% of Malaysian GDP and 3% of Indonesian GDP, so its role cannot be ignored. Both with pyrolysis and high efficient boilers, biomass waste can be used as an energy source and 100% of the PKS can be commercialized, but with pyrolysis is better because waste of EFB can also be processed, there are biochar product (while only ash if only with regular combustion) for Fertilizers saving in the palm oil plantations and the exhaust gases from the palm oil mill boilers are also clean because they burn gas (syngas) produced from the pyrolysis process.

Owls, Cobra Snakes or Liquid Smoke to Repel Mice at Palm Oil Plantations?

Mice are animals that disrupt various human activities so they must be expelled or killed. Many stories from farmers who experienced crop failure due to rampant rat pests. Likewise in palm oil plantations, rats will damage the palm fruit. Biological countermeasures are mostly carried out, namely with owls and cobra snakes. While other efforts that can be done is by liquid smoke. Aside from being used for fertilizer, liquid smoke can also be used to repel these mice. A strong aroma and an acidic nature will make the mice away from the palm oil trees that have been given liquid smoke. The longer the effect of liquid smoke on the palm oil tree the longer the mice away from the palm tree.

Liquid smoke does not harm humans and can be produced in large quantities. Besides that liquid smoke also comes from biomass (pyrolysis) so that it is an environmentally friendly chemical and from renewable sources. Empty bunches or EFB which have generally not been utilized by palm oil mills can be used for the production of liquid smoke. In addition to liquid smoke, biochar is also produced which is also very useful in the palm oil plantations, for more details, please read here. Production of liquid smoke and biochar from EFB will also be a solution to handling solid waste in the form of empty bunches. The production of biochar and liquid smoke for large scale can be done only with continuous pyrolysis units, for more details, please read here.

While when biochar and liquid smoke are used in oil palm plantations, the pyrolysis product in the form of syngas and biooil can be used for boiler fuel. When syngas and biooil are used as fuel, palm kernel shells and a number of mesocarp fibers can be sold or exported like CPO. PKS (palm kernel shell) or shell can be exported directly to Japan or Korea. Whereas mesocarp fiber can be made pellets or briquettes before being exported. Production of pellets or briquettes from mesocarp fiber is almost the same as the production of wood pellets or sawdust briquettes, for reference can be read here and here.

Back to the laptop. So the production of liquid smoke from pyrolysis of empty palm bunches is more likely to be a solution to overcome rat pests in addition to various other advantages for palm oil plantations and mills. In addition, liquid smoke can also be used for fertilizers and is not harmful. Even to optimize the control of rodent pests is very possible with a combination of liquid smoke with owls and cobra snakes.

Production of Biophenol, Bioformaldehyde and Wood Adhesive from Pyrolysis Liquid Products

The byproducts of biomass (slow) pyrolysis are liquid and gas products. The liquid products consist of biooil and biomass vinegar (pyroligneous acid). Biooils can be directly used as fuel with a particular burner, or can also be upgraded to the vehicle fuel. Meanwhile, if used for non-energy products, can be used for the production of green chemical or renewable chemicals such as BioFormaldehyde and wood adhesive. While the aqueous phase of pyrolysis liquid product that is biomass vinegar (pyroligneous acid) can be used for feedstock biophenol production. Previously biomass vinegar has been known for various uses such as latex coagulant, anti-termite and fertilizer. While the biophenol production process scheme of biomass vinegar as follows.

Global consumption for phenol currently reaches 20 million tons or worth 20 billion US dollars (280 trillion rupiah). Renewable phenol or biophenol can substitute phenol which has been produced based on petroleum. Excess heat and excess syngas from the pyrolysis process can be used for the production process of the biophenol as energy sources. An integrated and efficient production unit will produce highly competitive products, such as the pyrolysis process which is primarily charcoal, and from its by-products made derivative products that are desperately needed today.

Syngas Cleaning And Operation Time For Private/Independent Power Providers (IPP)

The continuity and stability of the electricity supply to the buyer is the most important thing for the private power provider or the Independent Power Producer (IPP). Electrical buyers in general are government through PLN or industry. To be able to provide such a continuous and stable electricity supply, IPP strives in such a way in a variety of ways including its various process engineering and also the operational. Biomass is a renewable energy source for electricity production that has many advantages especially in Indonesia, for example when wind and water (hydro) power plants are severely affected by weather conditions, the biomass power plant is not affected. Even high rainfall and tropical climate will increase the production of biomass as a source of energy. Related to the use of gas from biomass there are two routes to produce gas that is biology route and thermochemical route. The biological route is by fermentation in the digester, while the thermal route with gasification and pyrolysis. The characteristics of the raw material will determine the choice of technology, whether by biological route or thermochemical. Liquid waste or high water content and easy rot, such as livestock manure and palm oil mill effluent (POME) will use biological route, whereas biomass which is not easy to decompose such as woody biomass thermochemical route becomes the choice.

Why need to extract gas from the biomass? This is in addition to improving efficiency, also facilitate the utilization. Even by extracting the gas will also produce a number of economic value-added byproducts, for example with pyrolysis technology in addition to generating electricity, by-products such as charcoal, biooil, and biomass vinegar (liquid smoke). The economic value of these byproducts are bigger than the electricity production. The gas composition of the various biomasses also varies, depending on the biomass and the technology used, for example in biogas of large methane gas composition (55-75%), gasification of methane gas composition 0.5-3% while in pyrolysis gas composition methane 4-11%. Gas engine is a equipment or device commonly used to convert the combustible gas into electricity. Gas turbine although efficiency is higher but rarely used because of operational and maintenance factors are more difficult. Steam turbine is also rarely used and commonly used in large capacity power plants (> 20 MW). While Stirling engine and ORC (Organic Rankine Cycle) technology can also use gas from the biomass, but it is not specific because both Stirling engine and ORC only require heat for its operation and it does not have to be from gas. Practically both technologies above are using a lot of combustion to obtain the required heat.

Stirling Engine

ORC Technology

Gas Turbine

Gas Engine

The problem of purity or cleanliness of the gas that resulted in the operation of private power plants (IPP) received serious attention. The cleaner the gas and the stable the gas supply so the more stable the operation of the power plant and the opposite. The purchaser or user of electricity also requires the amount of electricity supply and tolerance to the breaking or shutting down of electricity at a certain time which must be fulfilled by the provider or private power producer. Various gas cleaning technologies have been used to obtain clean and stable gas supply to the converting equipments used. Gas cleaning technology in addition must be cheap and also easy to use so that electricity providers remain profitable. In general, the gas cleaning technology is to clean the gas from its impurities including also reduce or eliminate the gases that potentially disrupt the operation of such conversion equipments. For example CO2 and H2S gases in biogas process or tar in gasification and pyrolysis. 

Water scrubber (absorber) and stripper unit for biogas refinery

JF BioCarbon continuous pyrolysis technology is the best choice of electricity production from biomass with thermal route. This is in addition to generated electricity, also produced side products that are not less profitable, namely charcoal, biooil, and biomass vinegar. Then how about cleaning the gas so that the power supply electricity continuously? With a number of line cleaning units that work alternately, the continuity of the supply of clean gas can continue to run so also with the supply of electricity. A number of sensors are installed to ensure the cleanliness of the gas. Downtime or power outages will be reduced or even eliminated. Sufficient gas cleaning will ensure the continuous operation of the gas engine generator as a conversion unit from pyrolysis gas (chemical energy) to heat and mechanical energy (reciprocating engine in gas engine) and generate electricity. It is time for private power companies (IPP) to consider slowpyrolysis technology to continue as a wise and best choice for the production of electricity from biomass and a number of byproducts that are very profitable.

"Carbon Farming" For Palm Oil Plantation Part 5: Organic Palm Oil Plantations

Although currently not pictured on organic palm oil plantations. But organic palm oil plantation is possible in the coming era. Biochar application on palm oil plantation which is very effective for the home of microbes so as to enrich the soil. Microbes such as mooring N and so can be inoculated in the biochar application. While the nutritional requirements of bacteria in biochar will then be supplied from manure, so the integration of oil palm plantations and cattle ranches is imperative.

When this has been done then the contribution to saving the environment and food security is huge. Substantial revenue will come from the amount of carbon absorbed by the application of biochar through mechanisms such as CDM and organic palm oil products has its own market segment.

photo is taken from here

The discovery of Terra Preta Soil sites in East Kalimantan Will Accelerate the Implementation of Biochar in Indonesia

One proof will be more meaningful than a thousand promises. The recent discovery of Terra Preta soil in Malinau, East Kalimantan province make more people pay attention to biochar, which will accelerate the implementation of biochar and grow a variety of biochar industries in various regions in Indonesia and Southeast Asia.

To find out the news, please read the following article:

here and here.

Effect of Heating Rate in Pyrolysis Process

The rate of heating of the biomass particle has an important influence on yield and composition of the product. Rapid heating to a moderate temperature (400-600 oC) yields higher volatiles and hence more liquid, while slower heating to that temperature produces more char. The operating parameters of a pyrolyzer are adjusted to meet the requirement of the final product of interest. Tentative design norms for heating in a pyrolyzer include the following :

-To maximize char production, use a slow heating rate (<0.01-2.0 oC/s), a low final temperature, and a long gas residence time.
-To maximize liquid yield, use a high heating rate, a moderate final temperature (450-600 oC), and a short gas resiedence time.
-To maximize gas production, use a slow heating rate, a high final temperature (700-900 oC), and a long gas residence time.

Production of charcoal through carbonization uses the first norm, more detail about our pyrolyzer please click here or if you want more considerations about charcoal production please click here.

Selection of Pyrolysis Technology to Produce Charcoal from Biomass

Pyrolysis is a thermochemical decomposition of biomass into a range of useful  products, either in the total absence of oxidizing agents or with a limited supply that does not permit gasification to an appreciable extent. It is one of several  reaction steps or zones observed in a gasifier if we use gasification application. During pyrolysis, large complex hydrocarbon molecules of biomass break down into relatively smaller and simpler molecules of gas, liquid, and char.

Pyrolysis has similarity to and some overlap with processes like cracking, devolatilization, carbonization, dry distillation, destructive distillation, and thermolysis, but it has no similarity with the gasification process, which involves chemical reactions with an external agent known as gasification medium. Pyrol-ysis of biomass is typically carried out in a relatively low temperature range of 300 to 650 °C compared to 800 to 1000 °C for gasification. Other review the difference between pyrolysis and gasification, please click here.

The product of pyrolysis depends on the design of the pyrolyzer, the physical and chemical characteristics of the biomass, and important operating parameters such as

-  Heating rate

-  Final temperature (pyrolysis temperature)

-  Residence time in the reaction zone

Besides these, the tar and the yields of other products depend on (1) pressure,  (2) ambient gas composition, and (3) presence of mineral catalysts (Shafizadeh, 1984).

By changing the final temperature and the heating rate, it is possible to change the relative yields of the solid, liquid, and gaseous products of pyrolysis.  Rapid heating yields higher volatiles and more reactive char than produced by  a slower heating process; slower heating rate and longer residence time result in secondary char produced from a reaction between the primary char and the volatiles.

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Type of Pyrolysis

Based on heating rate, pyrolysis may be broadly classified as slow and fast. It is considered slow if the time, theating, required to heat the fuel to the pyrolysis temperature is much longer than the characteristic pyrolysis reaction time,  tr, and vice versa. That is:

-Slow pyrolysis: theating is bigger than tr

-Fast pyrolysis: theating is smaller tr

These criteria may be expressed in terms of heating rate as well, assuming a simple linear heating rate (Tpyr/theating, K/s). The characteristic reaction time, tr, for a single reaction is taken as the reciprocal of the rate constant,  k, evaluated at the pyrolysis temperature (Probstein and Hicks, 2006, p. 63).

There are a few other variants depending on the medium in and pressure at which the pyrolysis is carried out. Given specific operating conditions, each process has its characteristic products and applications. In the following list, the first two types are based on the heating rate while the third is based on the environment or medium in which the pyrolysis is carried out: (1) slow pyrolysis, (2) fast pyrolysis, and (3) hydropyrolysis.

Slow and fast pyrolysis are carried out generally in the absence of a medium.  Two other types are conducted in a specific medium: (1) hydrous pyrolysis (in H2O) and (2) hydropyrolysis (in H2). These types are used mainly for the production of chemicals.

In slow pyrolysis, the residence time of vapor in the pyrolysis zone (vapor residence time) is on the order of minutes or longer. This process is used primarily for char production and is broken down into two types: (1) carbonization and (2) conventional.

In fast pyrolysis, the vapor residence time is on the order of seconds or milliseconds. This type of pyrolysis, used primarily for the production of bio-oil and gas, is of two main types: (1) flash and (2) ultra-rapid. Carbonization produces mainly charcoal; fast pyrolysis processes target production of liquid or  gas.

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Production of charcoal through Pyrolysis

Carbon is a preferred product of biomass pyrolysis at a moderate temperature.  Thermodynamic equilibrium calculation shows that the char yield of most biomass may not exceed 35%. See table below gives the theoretical equilibrium yield of biomass at different temperatures. Assuming that cellulose represents biomass, the stoichiometric equation for production of charcoal (Antal, 2003) may be written as :

 

Charcoal production from biomass requires slow heating for a long duration but at a relatively low temperature of around 400 °C. An extreme example of a pyrolysis or carbonization is in the coke oven in an iron and steel plant, which pyrolyzes (carbonizes) coking coal to produce hard coke used for iron extraction. This is an indirectly pyrolyzer that operates at a temperature exceeding 1000 °C and for a long period of time to maximize gas and solid coke production.

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The best biochar  for improving soil quality (agricultural application) can be produced with slow pyrolysis process, more review on this, please click here.  The best charcoal for activated carbon production also can be produced with this process, more explanation please click here. We can also produce high fixed carbon charcoal with this technology, read more click here. In simple words we will produce charcoal as you wish.